This paper described the mechanism of chloride induced stress corrosion cracking of oil tube as a result of improper material selection and lack of maintenance. In austenitic stainless steel, the main forms of corrosion are pitting and stress corrosion cracking caused by chlorides. Chlorideassisted stresscorrosion cracking in type 316. Table 6 lists the relative corrosion resistance of the aisi standard numbered stainless steels in seven broad categories of corrosive environments. Chloride stress corrosion cracking and 316 stainless steel. Deterioration by clscc can lead to failures that have the potential to release. Chloride stress corrosion cracking in austenitic stainless. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. Stress corrosion cracking of aisi 304 and aisi 316.
This alloy exhibits superior resistance to stresscorrosion cracking in boiling 2040% sulfuric acid. The actual pitting corrosion phenomenon is shown on propeller shaft of high speed craft, and the pit depth was measured with dial. Table 7 details more specific environments in which vari. Chloride stress corrosion cracking stainless steel the three conditions that must be present for chloride stress corrosion to occur are as follows. Chloride stress corrosion cracking and 316 stainless steel chloride stress corrosion cracking and 316 stainless steel beh188 mechanical op 19 jul 11 17. Ss 316 austenitic stainless steel grade steelindo persada. The combination of the high molybdenum and chromium content, along with the addition of tungsten, make alloy c276 nickel alloy plate highly resistant to chloride stress corrosion cracking, pitting, crevice corrosion and general corrosion. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. In this study the influence of operating conditions such as chloride concentration, temperature on stress corrosion cracking of austenitic stainless steel will. The chemical composition and mechanical properties of the gauge cover alloy are shown in table 3, table 4, indicating 316 ss stainless steel. There are many charts you can find on the internet that show this relationship. The synergetic effect of those alloy elements promotes a higher. If this is a potable water as described,there is no reason to consider anything but carbon or galvanized steel.
Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Scc can occur typically in hot water tanks or swimming pools. Effects of chloride and oxygen on stress corrosion cracking of cold worked 316316l austenitic stainless steel in high temperature water article in corrosion science 110 april 2016 with 117 reads. Duplex grades are usually divided into three subgroups based on their corrosion resistance. This paper described the mechanism of chlorideinduced stress corrosion cracking of oil tube as a result of. Corrosion is a serious development that can lead to perforations of the tubing wall and the escape, under pressure, of highly flammable chemicals. Pitting corrosion of a stainless steel is illustrated in the figure 1. This mode of attack is termed stress corrosion cracking scc. Stress corrosion cracking scc is a common issue with many specialty alloys. It is found that the stress vs timetofailure curves for both alloys are divided into three regions that are dominated by either stress, scc, or.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. External chloride stress corrosion cracking of stainless. A maximum temperature of 60 deg c is given presumably to avoid stress corrosion cracking but with regard to chloride concentration limits it says any combination of chloride concentration and in situ ph occurring in production environments. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The standard 304304l and 316 316l grades are most susceptible. What is the maximum chloride in ppm that can be allowed in. Stress corrosion cracking of sensitized type 304 stainless. Stress corrosion cracking susceptibility of sensitized. Etienne, stress corrosion cracking in austenitic stainless steel fixings. There is a synergistic relationship between dissolved oxygen and the chloride level.
The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Sensor requirements for detection and characterization of. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Chloride stress corrosion cracking and 316 stainless steel edstainless materials 20 jul 11 23. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Effect of chloride deposition on stress corrosion cracking of 316l stainless steel used for intermediate level radioactive waste containers.
Hse research report rr902 chloride stress corrosion cracking in austenitic stainless steel describes the process of chloride stress corrosion cracking in austenitic stainless steel and how to assess susceptibility to this degradation mechanism. Corrosion of 316 stainless steel tubing has been observed in offshore applications around the world. Stainless steel deadlegs which collect chloride contaminated water instrument tubing that is normally not welded but contains high residual stresses comes in. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. If you you have temperatures above 150f,you could have stress corrosion cracking of 316 although unlikely below 200 f. Chloride stress corrosion cracking inspectioneering.
Austenitic steels of type astm 304 and 316 austenitic steels have limited resistance to stress corrosion cracking scc, even at very low chloride contents and temperatures. Chloride stress corrosion cracking and 316 stainless steel sjones petroleum 20 jul 11 03. High residual or applied stress, temperature above 6571c 150160f and chlorides increase the likelihood of cscc. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Type 304 and 316 since it is highly resistant to chloride stress corrosion cracking and is about twice as strong. Three underlying factors must be present to cause scc. Corrosion behaviour of type 316l stainless steel in hot. Behaviour of stress corrosion cracking of austenitic stainless. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Chloride corrosion of carbon steel pipe engineering. Effects of chloride and oxygen on stress corrosion.
Oct 20, 2019 the corrosion behaviour of type 316l stainless steel in aqueous 3050 wt%. Although no stainless steel grade is totally immune. This limits the usefulness of austenitic stainless steel for containing water with higher than a few ppm content of chlorides at temperatures above 50 c. Chloride stress corrosion cracking methods of minimizing. The 304 and 304l 188 stainless steel alloys have been utilized very successfully in fresh waters containing low levels of chloride ion of up to 100 ppm. In all cases of failure by stress corrosion cracking, the following three factors must be present. Effects of chloride and oxygen on stress corrosion cracking. The molybdenum gives 316 better overall corrosion resistant properties than grade 304, particularly higher resistance to pitting and crevice corrosion in chloride environments. Apr 14, 2015 cracking of this ring therefore presents a serious loss of containment risk. This level of chloride is considered to be the limit for the 188 alloys, particularly if crevices are present. Higher levels of chloride might cause crevice corrosion and pitting. During investigation many branched cracks were observed on the external surface of the gauge cover grown from the pits perpendicular to the cylinder axis. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries.
The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. The potential for stress corrosion cracking scc of welded stainlesssteel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. Stress corrosion cracking of aisi 304 and aisi 316 austenitic. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. At 50c they can withstand about 100 ppm of chlorides.
Chloride stress corrosion cracking clscc is one the most common reasons why austenitic. Different kinds of corrosion on stainless steel montanstahl. If the cl is present as hcl you have a problem that 316 wont solve. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The type of corrosion is most commonly local in the presence of chlorides, i. Temperatures typically need be in excess of 120of for scc in stainless steel. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. The higher nickel and molybdenum content in this grade allows it to demonstrate better overall corrosion resistant properties than the 304 alloy, which is especially true in pitting and crevice corrosion within chloride environments. Chloride ions are present in the environment dissolved oxygen is present in the environment metal is under tensile stress austenitic stainless steel is a non magnetic alloy consisting of iron. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Alloy c276 nickel alloy plate has excellent corrosion resistance in both oxidizing and reducing environments. Chloride stress corrosion cracking cscc is a type of intergranular corrosion.
Chloride stress corrosion cracking in austenitic stainless steel. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. Sour service limits of dualcertified 316316l steel twi. The 254smo 1 uns s31254 is a stainless steel that contains higher quantities of chromium, nickel, molybdenum and nitrogen than common stainless steels, such as 316, 316l and 304. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. The stress corrosion cracking scc of a commercial austenitic stainless steel type 316 was investigated as a function of sensitizing temperature 8000 k and test temperature 333373 k. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. This paper presents a fusion welding process that was developed for snf canister repair.
The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Corrosive conditions for stainless steel can be the chloride depositions from a marine atmosphere on the steel surface in a humid atmosphere these, conditions may alter the choice of steel grade to a more corrosion resistant alloy. On the stress corrosion cracking and hydrogen embrittlement. It can be concluded that the formation of the pits and the presence of stress can lead to clscc failure of plates.
The results indicate that pressure memory gauge cover failed due to chloride stress corrosion cracking clscc. Chlorideinduced stress corrosion cracking of 316 stainless. The gauge cover alloy was type aisi 316 stainless steel. Stress corrosion cracking scc of austenitic stainless steels of types 316 was investigated as a function of applied stress at room temperature in sodium chloride. Alloy 20 carpenter 20 is an austenitic stainless steel possessing excellent resistance to hot sulfuric acid and many other aggressive environments which would readily attack type 316 stainless. Effect of chloride deposition on stress corrosion cracking. Susceptibility to stress corrosion cracking of 254smo ss. Stainless steels are more resistant to general corrosion compared with carbon steel. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. The 316 alloy is a molybdenumbearing austenitic stainless steel that contains 18% chromium, 8% nickel, and 23% molybdenum. Naoh at temperatures up to 90 c has been elucidated.
The standard 304304l and 316316l grades are most susceptible. Chloride stress corrosion cracking ssina specialty steel. Pitting and crevice corrosion of offshore stainless steel. Methods of minimizing chloride stress corrosion cracking. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. Cracking of this ring therefore presents a serious loss of containment risk. If you seriously want a corrosionproof shaft, you may want to consider a ceramic and start looking at solgel technology to coat a stainless shaft. Chloride stress corrosion involves selective attack of a metal along its grain boundaries.
Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress corrosion cracking susceptibility of sensitized type. I have been reading into stress corrosion cracking scc caused by chlorides, which i understand can be quite an issue. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride. The presence of chloride in the eds spectrum also confirms the contribution of cl in pitting corrosion of the protective layer of 316 stainless steel plates. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur.
Stress corrosion cracking of an austenitic stainless steel in. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of. Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316. The stress corrosion cracking scc of aisi 304 and aisi 316 austenitic stainless steels in 0. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Stress corrosion cracking facts and how to reduce the risk. Corrosion of unprotected carbon steel occurs even inside reinforced. Exposure to room temperature environment showed parabolic weight loss behaviour, with corrosion rates of up to 0. Stress corrosion cracking scc of austenitic stainless steels of types 316. As a general rule, if the wetted parts of the equipment are manufactured from iron, steel, stainless steel or bronze, and they are showing no signs of corrosion, grade 316 stainless is acceptable as long as you do not use stainless steel springs. The effect of alloying elements and how these elements affect the electrochemical response in 50% naoh environments can be assessed, by comparing individual alloy responses. It depends on the grade of stainless steel and the temperature. Facts in brief about stress corrosion cracking scc.
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